Journal
RUSSIAN CHEMICAL BULLETIN
Volume 66, Issue 4, Pages 690-693Publisher
SPRINGER
DOI: 10.1007/s11172-017-1793-9
Keywords
2-methallylsulfanyl-4(3H)-pyrimidinones; 2-prenylsulfanylpyrimidin-4(3H)-ones; hydrochlorination; 2-(3-chloro-3-methyl-1-butylsulfanyl)-6-trifluoromethylpyrimidin-4(3H)-ones; heterocyclization; pyrimidothiazines; X-ray diffraction analysis
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Hydrochloric acid reacts with 5-ethyl-2-methallylsulfanyl-6-methylpyrimidin-4(3H)-ones to protonate the nitrogen atom; it adds to the double bond of 2-prenylsulfanyl-6-(trifluoromethyl)pyrimidin-4(3H)-one and gives the addition and heterocyclization products in the case of 2-prenylsulfanyl-6-methylpyrimidin-4(3H)-one.
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