Journal
ADSORPTION SCIENCE & TECHNOLOGY
Volume 36, Issue 1-2, Pages 625-639Publisher
SAGE PUBLICATIONS INC
DOI: 10.1177/0263617417713573
Keywords
CO2 adsorption; cooperative adsorption; optimal pore size; carbon nanotube; activated carbon
Funding
- Japan Society for the Promotion of Science KAKENHI [26706001, 15K12261]
- Futaba Electronics Memorial Foundation
- New Energy and Industrial Technology Development Organization (NEDO) in Japan
- Grants-in-Aid for Scientific Research [15K05583, 15K12261] Funding Source: KAKEN
Ask authors/readers for more resources
Separation of CO2 based on adsorption, absorption, and membrane techniques is a crucial technology necessary to address current global warming issues. Porous media are essential for all these approaches and understanding the nature of the porous structure is important for achieving highly efficient CO2 adsorption. Porous carbon is considered to be a suitable porous media for investigating the fundamental mechanisms of CO2 adsorption, because of its simple morphology and its availability in a wide range of well-defined pore sizes. In this study, we investigated the dependence of CO2 adsorption on pore structures such as pore size, volume, and specific surface area. We also studied slit-shaped and cylindrical pore morphologies based on activated carbon fibers of 0.6-1.7nm and carbon nanotubes of 1-5nm, respectively, with relatively uniform structures. Porous media with larger specific surface areas gave higher CO2 adsorption densities than those of media having larger pore volumes. Narrower pores gave higher adsorption densities because of deep adsorption potential wells. However, at a higher pressure CO2 adsorption densities increased again in nanopores including micropores and small mesopores. The optimal pore size ranges of CO2 adsorption in the slit-shaped and cylindrical carbon pores were 0.4-1.2 and 1.0-2.0nm, respectively, although a high adsorption density was only expected for the narrow carbon nanopores from adsorption potentials. The wider nanopore ranges than expected nanopore ranges are reasonable when considering intermolecular interactions in addition to CO2-carbon pore interactions. Therefore, cooperative adsorption among CO2 in relatively narrow nanopores can allow for high density and high capacity adsorption.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available