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Kinetics, thermodynamics, and isotherm study on the removal of methylene blue dye by adsorption via copper modified activated carbon

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 44, Issue 4, Pages 2231-2250

Publisher

SPRINGER
DOI: 10.1007/s11164-017-3225-8

Keywords

Copper modified AC; Methylene blue; Isotherm; Kinetics; Thermodynamics

Funding

  1. National Natural Science Foundation of China [21567013, 51504119]
  2. China Scholarship Council [201608740012]
  3. Yunnan Applied Basic Research Project [2015FB129]
  4. Yunnan Provincial Science and Technology Innovation Talents Scheme-Technological Leading Talent [2013HA002]
  5. National Natural Science Foundation of China [21567013, 51504119]
  6. China Scholarship Council [201608740012]
  7. Yunnan Applied Basic Research Project [2015FB129]
  8. Yunnan Provincial Science and Technology Innovation Talents Scheme-Technological Leading Talent [2013HA002]

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Copper modified activated carbon was explored by N-2 adsorption, XRD, SEM, EDX and FT-IR. The parameters of the optimal conditions, including the loading temperature, heating time, heating rate, ionic concentration and dipping time, were 450 A degrees C, 40 min, 25 A degrees C/min, 0.1 mol/L and 12 h, respectively. Copper nanoparticles were uniformly arranged on the carbon surface according to SEM analysis. The aqueous solution temperature, initial dose and adsorbent dose of copper modified AC were the parameters of the simultaneous experiment. The Langmuir isotherm model was revealed according to the applicable experimental data, the kinetic data were fit with a pseudo-second-order equation model, and the thermodynamic parameters indicated that MB adsorption was an endothermic and spontaneous process.

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