Journal
RARE METALS
Volume 36, Issue 5, Pages 321-338Publisher
NONFERROUS METALS SOC CHINA
DOI: 10.1007/s12598-017-0899-4
Keywords
Antimony; Intermetallic compound; Alloy; Anode; Sodium-ion battery; Lithium-ion battery
Funding
- National Key Research and Development Program of China [2016YFA0202603]
- National Basic Research Program of China [2013CB934103]
- Program of Introducing Talents of Discipline to Universities [B17034]
- National Natural Science Foundation of China [51521001]
- National Natural Science Fund for Distinguished Young Scholars [51425204]
- Fundamental Research Funds for the Central Universities [2016III001, 2016-JL-004]
- China Scholarship Council [201606955096]
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The development of alternative electrode materials with high energy densities and power densities for batteries has been actively pursued to satisfy the power demands for electronic devices and hybrid electric vehicles. Recently, antimony (Sb)-based intermetallic compounds have attracted considerable research interests as new candidate anode materials for high-performance lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to their high theoretical capacity and suitable operating voltage. However, these intermetallic systems undergo large volume change during charge and discharge processes, which prohibits them from practical application. The rational construction of advanced anode with unique structures has been proved to be an effective approach to enhance its electrochemical performance. This review highlights the recent progress in improving and understanding the electrochemical performances of various Sb-based intermetallic compound anodes. The developments of synthesis and construction of Sb-based intermetallic compounds are systematically summarized. The electrochemical performances of various Sb-based intermetallic compound anodes are compared in its typical applications (LIBs or SIBs).
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