Journal
PURE AND APPLIED CHEMISTRY
Volume 89, Issue 3, Pages 311-330Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2016-1001
Keywords
aromatic C-H bonds; catalysis; chlorophosphine; dialkyl H-phosphonate; electrosynthesis; ICPC-21; metal complex; perfluoroalkylation; phosphonation; white phosphorus
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Funding
- Russian Science Foundation [14-23-00016]
- Russian Science Foundation [17-23-00002] Funding Source: Russian Science Foundation
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The development of practical, efficient and atom-economical methods of formation of carbon-phosphorus bonds remains a topic of considerable interest for the current synthetic organic chemistry and electrochemistry. This review summarizes selected topics from the recent publications with particular emphasis on phosphine and phosphine oxides formation from white phosphorus, chlorophosphines in electrocatalytic processes using aryl, hetaryl or perfluoroalkyl halides as reagents. This review includes selected highlights concerning recent progress in modification of catalytic systems for aromatic C-H bonds phosphonation involving metal-catalyzed ligand directed or metal-induced oxidative processes. Furthermore, a part of this review is devoted to phosphorylation of olefins with white phosphorus under reductive conditions in water-organic media. Finally, we have also documented recent advances in ferrocene C-H activation and phosphorylation.
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