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Recent advances in additive-enhanced magnesium hydride for hydrogen storage

Journal

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.pnsc.2016.12.016

Keywords

Hydrogen storage; MgH2; Additives; Alloying; Nanoscaling; Nanoconfinement

Funding

  1. Research Fund for the Doctoral Program of Higher Education of China [20120031110001]
  2. Tianjin Science Technology [10SYSYJC27600]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions

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The discovery of new hydrogen storage materials has greatly driven the entire hydrogen storage technology forward in the past decades. Magnesium hydride, which has a high hydrogen capacity and low cost, has been considered as one of the most promising candidates for hydrogen storage. Unfortunately, extensive efforts are still needed to better improve its hydrogen storage performance, since MgH2 suffers from high operation temperature, poor dehydrogenation kinetic, and unsatisfactory thermal management. In this paper, we present an overview of recent progress in improving thehydrogenation/de-hydrogenation performance of MgH2, with special emphases on the additive-enhanced MgH2 composites. Other widely used strategies (e. g. alloying, nanoscaling, nanoconfinement) in tuning the kinetics and thermodynamics of MgH2 are also presented.

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