Journal
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume 74, Issue -, Pages 799-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989018007077
Keywords
crystal structure; tin; Schiff base
Categories
Funding
- Sonatel Foundation
Ask authors/readers for more resources
The binuclear complex, [Sn-2(C4H9)(4)(C16H10N4O4)], contains two Sn4+ ions, connected by doubly N-deprotonated oxalylbis[(2-oxidobenzylidene)hydrazide] ligands, and each Sn4+ ion is linked to two tert-butyl groups. The coordination sphere of each Sn atom is best described as a distorted trigonal bipyramid. Each stannic ion in the complex is in a C2O2N environment. The two homologous parts of the doubly deprotonated ligand are located in trans positions with respect to the C-C bond of the oxalamide group. The oxalamide group exhibits an asymmetric coordination geometry, as seen by the slight difference between the C-O and C-N bond lengths. The three-dimensional network is a multilayer of complex molecules with no strong supramolecular interactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available