4.4 Review

Conjugated D-A terpolymers for organic field-effect transistors and solar cells

Journal

POLYMER JOURNAL
Volume 50, Issue 1, Pages 21-31

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/pj.2017.53

Keywords

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Funding

  1. NSFC [21372226, 21661132006, 21602208]
  2. Strategic Priority Research Program of the CAS [XDB12010300]
  3. 973 program [2013CB933501]
  4. Dr Research Program of Zhengzhou University of Light Industry [2015BSJJ041]

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The incorporation of additional electron donors or acceptors into the backbones of conjugated polymers with alternating donors and acceptors results in various conjugated D-A terpolymers. The presence of additional electron donors or acceptors in the conjugated backbones can modulate the electronic absorptions and highest occupied molecular orbital/lowest unoccupied molecular orbital levels, as well as interchain interactions and thin-film morphology. Because of these structural features, conjugated D-A terpolymers have been intensively investigated in recent years for applications in field-effect transistors and photovoltaic cells. In this review, we introduce the recent developments of conjugated D-A terpolymers with various combinations of electron donors and acceptors, and discuss the future perspectives for conjugated terpolymers.

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