4.6 Article

Nitrogen and Sulfur Self-Doped Activated Carbon Directly Derived from Elm Flower for High-Performance Supercapacitors

Journal

ACS OMEGA
Volume 3, Issue 4, Pages 4724-4732

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b00210

Keywords

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Funding

  1. National Natural Science Foundation of China [U1303291]
  2. Program for Changjiang Scholars and Innovative Research Team in University [IRT_15R46]
  3. Program of Science and Technology Innovation Team in Bingtuan [2015BD003]

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N,S-Doped activated carbon was directly prepared via a facile and cost-efficient hydrothermal reaction, followed by alkali activation of elm flower (EL)-derived biomass. The EL-derived activated carbon (ELAC) had N and S contents of 2.21 and 6.06 atom %, respectively, in addition to a high Brunauer-Emmett-Teller (BET) surface area of 2048.6 m(2) g(-1) and moderate pore volume of 0.88 cm(3) g(-1). Owing to its high BET surface area and N/S functional groups, ELAC achieved a specific capacitance of 275 F g(-1) at a current density of 1 A g(-1) and retained a capacitance of 216 F g(-1) at 20 A g(-1). In addition, a symmetric supercapacitor based on N, S-self-doped ELAC electrode provided a capacitance of 62 F g(-1) at a current density of 10 A g(-1), with maximum energy and power densities of 16.8 Wh kg(-1) and 600 W kg(-1), respectively. The capacitance retention was also high, at 87.2%, at 4 A g(-1) after 5000 cycles.

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