4.7 Article

Preparation of polythiophene microrods with ordered chain alignment using nanoporous coordination template

Journal

POLYMER CHEMISTRY
Volume 8, Issue 34, Pages 3077-+

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7py00309a

Keywords

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Funding

  1. CREST-JST
  2. Ministry of Education, Culture, Sports, Science and Technology, Government of Japan [2802]
  3. Grants-in-Aid for Scientific Research [16J11419, 2802] Funding Source: KAKEN

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The properties of polymeric materials can be amplified by macromolecular alignment. The highly ordered chain alignment of unsubstituted polythiophene, an unprocessable polymer, has been achieved using a porous coordination polymer (PCP) as a template. Due to the extended conjugation system, the obtained anisotropic polymer particles exhibit higher conductivity than that of polythiophene prepared by solution polymerization.

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