PVDF-ionic liquid modified clay nanocomposites: Phase changes and shish-kebab structure

Crystalline behaviour of PVDF nanocomposite with 1-alkyl-3-methylimidazolium modified montmorillonite clay was analyzed. The phase change from alpha to beta increased with alkyl chain length of the organic modifier in the filler; 1-alkyl-3-methylimidazolium clay and maximum conversion (99%) was observed for PVDF-1-hexadecyl-3-methylimidazolium modified clay composite with 2% loading. The phase conversionwas evident from X-ray diffraction, DSC analysis and improved electrical properties. AFM analysis of PVDF-1-butyl-3-methylimidazolium montmorillonite clay composite (PVDF-C4) showed a shishkebab structure while pristine PVDF and all other composites showed spherulite structures. Computational studies revealed that the extended chain alpha-phase forms the 'shish', the back bone and folded chain beta-phase forms the 'kebab'. This was further supported by the superior mechanical properties for PVDF-C4 composite. Present work shows that introducing ionic liquid modified MMT-clay within the PVDF matrix enables nucleation of electroactive b phase and the presence of equal content of alpha and beta phases can lead to the formation of self reinforced shish-kebab structures in PVDF. (C) 2017 Elsevier Ltd. All rights reserved.