Journal
POLYMER
Volume 110, Issue -, Pages 74-79Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2016.12.074
Keywords
Emulsion-template; Macroporous polymer; Diels-Alder polymerization; Self-healing
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Funding
- National Natural Scientific Foundation of China [51103042]
- Natural Science Foundation of Shanghai [16ZR1407800]
- Fundamental Research Funds for the Central Universities
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Emulsion-templated macroporous materials, known in the literature for many years as polyHlPEs, have found an increasing number of applications due to their well-defined structures. However, most of the emulsion-templated materials are synthesized using conventional radical polymerization, and most of the radical polymerization are thermally initiated. Expanding the polymerization mechanisms available for emulsion-templated material synthesis is still highly desired. In this work, macroporous polymers were firstly synthesized by Diels-Alder reaction of furan derivatives and bismaleimide within the continuous phase of particle-stabilized emulsions. These polymers have a well-defined controllable porous structure and good self-healing performance. (C) 2016 Elsevier Ltd. All rights reserved.
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