Journal
POLYMER
Volume 127, Issue -, Pages 203-213Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2017.09.012
Keywords
Polymer flammability; Thermosets; Pyrolysis-combustion flow calorimetry; Van Krevelen approach
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Funding
- ANR (Agence Nationale de la Recherche) [ANR-15-CE22-0007-04]
- Agence Nationale de la Recherche (ANR) [ANR-15-CE22-0007] Funding Source: Agence Nationale de la Recherche (ANR)
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From a set of around 30 thermosets (polycyanurates, polybenzoxazines, epoxy and phtalonitrile resins) tested in pyrolysis-combustion flow calorimetry, the contributions to flammability of 14 new chemical groups are calculated using a method previously proposed and validated. The flammability properties include total heat release, heat release capacity and char content. The comparison between these groups allows drawing some consistent conclusions about the best structures in terms of flammability. Especially, the aromaticity, the number of covalent bonds between the considered chemical group and the neighboring groups and the presence of heteroatoms (O, N) in the structure are highlighted. (C) 2017 Elsevier Ltd. All rights reserved.
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