Journal
POLYHEDRON
Volume 128, Issue -, Pages 198-202Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2017.02.046
Keywords
Iron complexes; Bipyridine ligand; Cross-coupling reaction; X-ray diffraction study
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Funding
- JSPS KAKENHI [25410063]
- Institute for Chemical Research, Kyoto University [2016-22]
- Grants-in-Aid for Scientific Research [25410063, 17K05805] Funding Source: KAKEN
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Three known iron(II) complexes bearing a bipyridine ligand, [FeCl2(bpy)(2)] (1), [FeCl2(bpy)](2) (2) and [FeCl2(dmbpy)] (3) (bpy = 2,2'-bipyridine and dmbpy = 6,6'-dimethyl-2,2'-bipyridine) were employed for the cross-coupling reaction of bromocyclohexane (4) with phenylmagnesium bromide (5). These complexes catalyzed the cross-coupling reaction. Among the three catalysts, complex 2 acted as an effective catalyst to afford the cross-coupled product phenylcyclohexane (6) in 92% yield. The X-ray crystal structure analyses of 2 and 3 were demonstrated. (C) 2017 Elsevier Ltd. All rights reserved.
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