Journal
POLYHEDRON
Volume 138, Issue -, Pages 1-6Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2017.09.007
Keywords
Half-sandwich; Ruthenium; Complex; Catalyst; Nitrile
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Funding
- National Nature Science Foundation of China [21102004]
- Natural Science Foundation of Anhui Province [1708085MB44]
- Natural Science Foundation of the Anhui Higher Education Institutions of China [KJ2016A845]
- Anhui Normal University
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Three ruthenium(II) p-cymene complexes containing oxygen-nitrogen mixed ligands [Ru(p-cymene)LCI] [HL = 2-(4,5-dihydrooxazol-2-yl)phenol (2a); HL = 2-(4,5-dihydrothiazol-2-yl)phenol (2b); HL = 2-(5,6-dihydro-4H-1,3-oxazin-2-yl)phenol (2c)] have been synthesized and characterized. All half-sandwich ruthenium complexes were fully characterized by H-1 and C-13 NMR spectra, elemental analyses and infrared spectrometry. The molecular structure of ruthenium complex 2c was further confirmed by single crystal X-ray diffraction methods. Furthermore, these half-sandwich ruthenium complexes are active catalysts for the hydration of nitriles to amides in the presence of sodium hydroxide in isopropanol. (C) 2017 Elsevier Ltd. All rights reserved.
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