4.6 Article

Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 19, Issue 2, Pages 971-975

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp07207k

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Funding

  1. National Science Foundation (NSF), Chemical Catalysis Program [CHE-1566138]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1566138] Funding Source: National Science Foundation

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The adsorption of alkali and tetraalkylammonium cations on Pt is investigated using surface enhanced infrared absorption spectroscopy and carbon monoxide as a probe molecule. Alkali cations exhibit a stronger adsorption than organic cations, with potassium showing the strongest effect, followed by sodium and lithium.

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