4.6 Article

Beta transmutations in apatites with ferric iron as an electron acceptor - implication for nuclear waste form development

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 19, Issue 37, Pages 25487-25497

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cp02846f

Keywords

-

Funding

  1. Center for Performance and Design of Nuclear Waste Forms and Containers (calculations, analysis, and writing), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DE-SC0016584]
  2. DOE Office of Nuclear Energy's Nuclear Energy University Programs (calculations and analysis) [DE-AC07-05ID14517]
  3. Office of Science of the U.S. Department of Energy [DE-AC02-05CH11231]

Ask authors/readers for more resources

Apatite-structured materials have been considered for the immobilization of a number of fission products from reprocessing nuclear fuel because of their chemical durability as well as compositional and structural flexibility. It is hypothesized that the effect of beta decay on the stability can be mitigated by introducing an appropriate electron acceptor at the neighboring sites in the structure. The decay series Cs-137 -> Ba-137 and Sr-90 -> Y-90 -> Zr-90 were investigated using a spin-polarized DFT approach to test the hypothesis. Apatites with compositions of Ca-10(PO4)(6)F-2 and Ca4Y6(SiO4)(6)F-2 were selected as model systems for the incorporation of radionuclides Cs and Sr, respectively. Ferric iron was introduced in the structure as an electron acceptor. Electron density of states, crystal and defect structures, and energies before and after beta decay were calculated. The calculated electron density of states suggests that the extra electron is localized at the ferric iron, which changes its oxidation state and becomes ferrous iron. The crystal and defect structures were analyzed based on the volume, lattice parameters, radial distribution functions, metal cation to coordinating oxygen distances, and the metaprism twist angle of the apatite crystal structure. The results show that there are minor changes in the crystal and defect structures of CsFeCa8(PO4)(6)F-2 with Cs+ and Fe3+ substitutions undergoing the Cs -> Ba transmutation, and of Ca3SrY4Fe2(SiO4)(6)F-2 with Sr2+ and Fe3+ substitutions undergoing the Sr -> Y -> Zr transmutations. The last decay change, from Y3+ -> Zr4+, causes relatively larger changes in the local defect structure around Zr involving the coordination environment but the change is not significant to the crystal structure. The results on calculated cohesive energy suggest that the transmutations Cs+ -> Ba2+ and Sr2+ -> Y3+ -> Zr4+ in both apatite compositions are energetically favorable, which is consistent with the minor structure distortions. Increased stability with favorable energetics and structural distortion by incorporating ferric ion is significant with respect without variable valence ions. The results confirm the structural and compositional adaptability of apatites upon beta transmutations. The study suggests that apatite-structured materials could be promising nuclear waste forms to mitigate the beta decay induced instability, by incorporating variable valence cations such as ferric iron in the structure. The study demonstrates a methodology which evaluates the structural stability of waste forms incorporating fission products undergoing beta decay.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available