Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 19, Issue 28, Pages 18162-18166Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cp01840a
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Funding
- China Scholarship Council (CSC)
- Ministry of Education and Science of the Republic of Serbia [OI 172043, OI 172035]
- National Natural Science Foundation of China (NSFC) [21271068]
- Natural Science Foundation of Hubei Province [2015CFA131]
- Wuhan Applied Basic Research Program [2014010101010020]
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A high resolution X-ray diffraction study has been carried out on [(C4H9)(4)N](2) [V6O13{(OCH2)(3)CCH2OCCH2CH3}(2)] (V6-C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion. A nucleophilic region localized near the organic moiety and an electrophilic region in the vicinity of the V6 core provide an overall description of charge-transfer behavior.
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