4.6 Article

Quantitative assessment of kosmotropicity of hydrated ionic liquids by nuclear magnetic resonance

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 19, Issue 12, Pages 8148-8151

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cp07463d

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Funding

  1. Japan Society for the Promotion of Science (KAKENHI) [26248049, 26810066]
  2. Women's Future Development Organization of Tokyo University of Agriculture and Technology
  3. Grants-in-Aid for Scientific Research [26810066] Funding Source: KAKEN

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Nuclear magnetic resonance studies revealed that the chemical shift of H2O in hydrated ionic liquids varied with their component ions. The variation reflected the formation of hydrogen bonding networks between ions and water molecules. The chemical shift relative to bulk water was used to quantitatively assess the kosmotropicity.

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