Journal
JOURNAL OF CHEMICAL SCIENCES
Volume 130, Issue 9, Pages -Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12039-018-1515-3
Keywords
Chromium(III) complexes; catalytic activities; polymerization; oxalate ion
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Funding
- National Science Centre, Poland [2015/19/N/ST5/00276]
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The cis- and trans-potassium bis(oxalato)diaquochromates(III) have been studied towards their catalytic activity for the 2-chloroallyl alcohol oligomerization. The geometric isomerism effect on the oligomerization products under mild reaction conditions has been investigated. The molecular masses and tactic structures of obtained poly(2-chloroallyl alcohols) have been compared and analyzed. The mechanisms of oligomerization processes have been proposed. It has been proven that two studied complexes - cis- and trans- are highly active catalysts for the oligomerization of the beta-olefin derivative.
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