4.4 Article

Thin Films of Copper (I) Iodide Doped with Iodine and Thiocyanate

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssa.201700520

Keywords

copper iodide; hole conducting materials; thiocyanate doping; transparent semiconductors

Funding

  1. UWG SRAP program
  2. COSM FRG program
  3. SEEP program

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It is found that thiocyanate (SCN) is an alternative dopant that greatly stabilizes the p-type semiconducting properties of CuI. Thiocyanate doping can be achieved by a complete removal of the excess iodine and introduction of thiocyanate via suitable precursors at ambient temperature. A method of removal of iodine from CuI before casting films is described. The electrical and optical properties of thiocyanate-doped CuI thin films are also discussed.

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