Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 192, Issue 6, Pages 695-699Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2017.1284838
Keywords
Phosphole oxide dimer; 7-phosphanorbornene oxide; reduction; borane; P-borane
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Funding
- Hungarian Research Development and Innovation Fund [K119202]
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The selective reduction and boronation of the P-phenyl phosphole oxide dimer applying BH3SMe2 as the reagent was investigated. The optimized protocol allowing the POPBH3 conversion at 26 degrees C in concentrated CH2Cl2 solution could be well extended also to a series of P-alkyl phosphole oxide dimers.
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