Journal
CURRENT OPINION IN ELECTROCHEMISTRY
Volume 9, Issue -, Pages 189-197Publisher
ELSEVIER
DOI: 10.1016/j.coelec.2018.03.038
Keywords
-
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC) [RGPIN-2014-04074]
- Catalysis Research for Polymer Electrolyte Fuel Cells (CaRPE-FC) Network
- Automotive Partnership Canada (APC) through NSERC [APCPJ-417858-11]
- NSERC Discovery Frontiers Program [RGPNM 477963-2015]
Ask authors/readers for more resources
This opinion piece centers around challenges involved in developing first-principles electrochemical methods. In recent years, theory and computation have become indispensable tools to navigate the parameter space that controls the activity and stability of electrocatalytic materials and electrochemical devices. Viable methods process as input details on materials structure, composition and reaction conditions. Their output includes metrics for stability and activity, phase diagrams, as well as mechanistic insights on reaction mechanisms and pathways. The core challenge, connecting input to output, is a self-consistency problem that couples the electrode potential to variables for the electronic structure of the solid electrode, solvent properties and ion distributions in the electrolyte as well as specific properties of a boundary region in-between. We will discuss a theoretical framework and computational approaches that strive to accomplish this feat.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available