4.7 Article

CuS nanoflowers/semipermeable collodion membrane composite for high-efficiency solar vapor generation

Journal

MATERIALS TODAY ENERGY
Volume 9, Issue -, Pages 285-294

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.mtener.2018.06.003

Keywords

CuS nanoflowers; SCM; Integrated structure; LSPRs; Solar vapor generation

Funding

  1. U.S. National Science Foundation [DMR-1609061]
  2. College of Arts and Sciences, University of Missouri - Kansas City
  3. National Key R & D Program of China [2016YFB0300700, 2016YFB0300704]
  4. State Key Development Program for Basic Research of China (973 project) [2014CB643306]
  5. NSF of Shanghai [17ZR1440900]
  6. National Nature Science Foundation of China [51602195]
  7. Doctoral Innovation Foundation of SMU [2016ycx037]
  8. Doctoral Excellent Thesis Project Foundation of SMU [2017BXLP005]

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The ever-dwindling freshwater sources and ever-increasing need for freshwater resources are regarded as two important concerns for current society. Solar vapor generation has proven to be an effective and reliable solar-driven technology to overcome these concerns. However, it is a big challenge to prepare low-cost and high-efficiency solar absorber for solar vapor generation. Herein, we report a novel structurally integrated solar absorber composed of CuS nanoflowers and semipermeable collodion membrane (SCM). Three-dimensional (3D) covellite CuS nanoflowers composed of nanosheets have been synthesized with a facile hydrothermal route and their morphology and structure are investigated with various analytical techniques. High solar vapor generation efficiencies of 68.6% and 81.2% were achieved with CuS/SCM under 1 and 4 sun irradiation, respectively, much higher than that of the CuS nanofluid. A stable solar vapor generation performance has been demonstrated over 20 cycles. These results display a promising potential of CuS/SCM as a solar-absorber for efficient solar vapor generation. (C) 2018 Elsevier Ltd. All rights reserved.

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