3.9 Article

Relationship between Commonly Used Adsorption Isotherm Equations Impedes Isotherm Selection

Journal

PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING
Volume 61, Issue 1, Pages 10-14

Publisher

BUDAPEST UNIV TECHNOLOGY ECONOMICS
DOI: 10.3311/PPch.10103

Keywords

isotherm fitting; bi-Langmuir isotherm; Freundlich isotherm; adsorption isotherm; binding site

Funding

  1. OTKA, Hungary [K120075]
  2. Erno Pungor Scholarship

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If the measured isotherm data of an adsorption system are well described by the Freundlich equation, then they can similarly well be described by the bi-Langmuir or tri-Langmuir model in most practical cases. This is proved by Monte Carlo simulation and by comparison of the mathematical functions of the respective isotherm models.

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