3.9 Article

Effect of Cyclic Butylene Terephthalate Oligomer on the Properties of Styrene-Butadiene and Acrylonitrile-Butadiene Rubbers

Journal

PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING
Volume 62, Issue 1, Pages 32-42

Publisher

BUDAPEST UNIV TECHNOLOGY ECONOMICS
DOI: 10.3311/PPch.10913

Keywords

nitrile rubber; styrene-butadiene bifunctional additive; cyclic butylene terephthalate oligomer; CBT; plasticizer; processing aid; semi-active filler

Funding

  1. OTKA Hungarian Scientific Research Fund in Hungary [K100294]

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In this work the effect of cyclic butylene terephthalate (CBT) was studied on the curing, rheological, morphological and mechanical properties of styrene butadiene rubber (SBR), oil extended styrene butadiene rubber (oSBR), acrylonitrile butadiene rubbers (NBR) with various acrylonitrile (AN) content and a carboxylated acrylonitrile butadiene rubber (XNBR). The effect of CBT on the oil resistance of the NBR and XNBR based compounds was also investigated. Viscosities of the uncured compounds were significantly decreased by CBT and it also acted as a semi-active filler, effectively reinforcing the tested rubbers, therefore it is suggested to be a bifunctional additive for tested rubbers. CBT also showed to have a positive effect on the oil resistance of NBR compounds.

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