Journal
BATTERIES-BASEL
Volume 4, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/batteries4030041
Keywords
polymer electrolyte; lithium glycerolate; lithium single-ion conductor
Funding
- Budget Integrato per la Ricerca Interdipartimentale-BIRD 2016 of the University of Padova [BIRD164837/16]
- Centro Studi di Economia e Tecnica dell'Energia Giorgio Levi Cases of the University of Padova
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The detailed study of the interplay between the physicochemical properties and the long-range charge migration mechanism of polymer electrolytes able to carry lithium ions is crucial in the development of next-generation lithium batteries. Glycerol exhibits a number of features (e.g., glass-forming behavior, low glass transition temperature, high flexibility of the backbone, and efficient coordination of lithium ions) that make it an appealing ion-conducting medium and a challenging building block in the preparation of new inorganic-organic polymer electrolytes. This work reports the preparation and the extensive investigation of a family of 11 electrolytes based on lithium glycerolate. The electrolytes have the formula C3H5(OH)(3-x)(OLi)(x), where 0 <= x <= 1. The elemental composition is evaluated by inductively coupled plasma atomic emission spectroscopy. The structure and interactions are studied by vibrational spectroscopies (FT-IR and micro-Raman). The thermal properties are gauged by modulated differential scanning calorimetry and thermogravimetric analysis. Finally, insights on the long-range charge migration mechanism and glycerol relaxation events are investigated via broadband electrical spectroscopy. Results show that in these electrolytes, glycerolate acts as a large and flexible macro-anion, bestowing to the material single-ion conductivity (1.99 x 10(-4) at 30 degrees C and 1.55 x 10(-2) S.cm(-1) at 150 degrees C for x = 0.250).
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