Journal
ACS OMEGA
Volume 3, Issue 8, Pages 8836-8842Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b01401
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Funding
- University of Helsinki Research Foundation
- Academy of Finland [264020, 265481]
- Academy of Finland (AKA) [264020, 265481, 265481, 264020] Funding Source: Academy of Finland (AKA)
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Bi(OTf)(3)center dot xH(2)O is a powerful catalyst for the dehydration of tertiary alcohols into alkenes in apolar solvents. The reaction proceeds smoothly and selectively, with amounts as low as 0.01 mol % catalyst, in yields up to 93%. Moreover, in polar solvents, Bi(OTf)(3)center dot xOH(2)O (0.1-1 mol %) selectively catalyzes the dimerization of the alcohols instead, forming new C-C bonds, in yields up to 96%. This mild, efficient, economic, and eco-friendly method is applicable across different chemical classes and amenable to several functional groups.
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