Ru(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates

A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C-C and C-N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner.