Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 8, Issue 1, Pages 195-202Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ee03045a
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Funding
- Samsung Advanced Institute of Technology
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We report on layered NaTiO2 as a potential anode material for Na-ion batteries. The material is prepared from only earth-abundant elements, delivers 152 mA h g(-1) of reversible capacity at C/10 rate, shows excellent cyclability with capacity retention over 98% after 60 cycles, and high rate capability. Furthermore, in situ X-ray diffraction analysis reveals a reversible O3-O'3 phase transition, including an unusual lattice parameter variation coupled to complicated Na vacancy orderings in a series of 2nd order phase transitions.
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