Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 8, Issue 12, Pages 3531-3538Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ee02074c
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Funding
- Sofja Kovalevskaja award of the Alexander von Humboldt Foundation
- National Natural Science Foundation of China [21171015, 21373195, 11202177]
- Recruitment Program of Global Experts
- program for New Century Excellent Talents in University [NCET-12-0515]
- Fundamental Research Funds for the Central Universities [WK2060140014, WK2060140016]
- Collaborative Innovation Center of Suzhou Nano Science and Technology
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Uniform yolk-shell Sn4P3@C nanospheres were facilely synthesized via a top-down phosphorized route with yolk-shell Sn@C nanospheres as the precursor. As anode materials for Na-ion batteries, they exhibit very high reversible capacity (790 mA h g(-1)), superior rate capability (reversible capabilities of 720, 651, 581, 505, and 421 mA h g(-1) at 0.2C, 0.4C, 0.8C, 1.5C, and 3C, respectively) and stable cycling performance (a high capacity of 360 mA h g(-1) at 1.5C after long 400 cycles).
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