Journal
ORGANOMETALLICS
Volume 36, Issue 22, Pages 4359-4362Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00691
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Funding
- National Key R&D Program of China [2016YFA0202900]
- National Basic Research Program of China (973 Program) [2015CB856600]
- NSFC [21332009, 21421091, 21572250]
- Strategic Priority Research Program of CAS [XDB20000000, QYZDYSSWSLH012]
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Amidation of N-containing heteroaryl ferrocenes with 1,4,2-dioxazol-5-ones as the amidated reagents was achieved via a Rh-catalyzed direct C-H functionalization reaction. Under mild reaction conditions, a wide range of N-ferrocenyl amides were obtained-in up to 99% yield. Transformations of the amide group were also feasible.
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