Journal
ORGANOMETALLICS
Volume 36, Issue 7, Pages 1345-1351Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00058
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Funding
- JSPS [JP16H01031]
- Grants-in-Aid for Scientific Research [17K05864, 16H01031] Funding Source: KAKEN
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Tin fluorides were found to be suitable electrophiles for the copper-catalyzed borylstannylation of terminal alkynes with bis(pinacolato)diboron to afford cis-vic-boryl(stannyl)alkenes straightforwardly. A fluorine atom proved to play a pivotal role in generating a key catalytic intermediate, a borylcopper species, both in the induction period and in the sigma-bond metathesis step.
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