Journal
ORGANIC LETTERS
Volume 19, Issue 6, Pages 1278-1281Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03898
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Funding
- European Research Council under the European Community's Seventh Framework Program (FP7)/ERC [307535]
- DAAD
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C-H oxygenations of synthetically meaningful sulfoximine benzamides were accomplished by a versatile ruthenium catalysis regime. The ruthenium(II) catalyst was characterized by excellent mono- and chemoselectivity as well as positional selectivity via facile base-assisted intramolecular electrophilic substitution-type (BIES) C-H activation. The synthetic utility of the approach was reflected by high functional group tolerance and sulfoximine removal in a traceless fashion.
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