Journal
ORGANIC LETTERS
Volume 19, Issue 15, Pages 4042-4045Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01795
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Funding
- National Natural Science Foundation of China [21672192, 21472176]
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The manganese-catalyzed addition of C-2 position of indoles to maleimides has been achieved under additive-free conditions. The manganese catalyst exhibits excellent chemo- and regioselectivity, good functional group compatibility, and high catalytic efficiency. The substrate scope can also be extended to maleates, ethyl acrylate, 1,4-dihydro-1,4-epoxynaphthalene, pyrroles, and 2-phenylpyridine, which further demonstrates the universality of this straightforward approach.
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