Journal
ORGANIC LETTERS
Volume 19, Issue 8, Pages 2150-2153Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00793
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Funding
- National Science Foundation [DGE-1144469]
- Shionogi Co., Ltd.
- American Cancer Society Research Scholar and Heritage Medical Research Institute Investigator
- NIH [NIGMS RGM097582-01, R35GM118191]
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An enantioselective Ni-catalyzed cross-coupling of NT-hyciroxyphthalimide esters with Vinyl bromides is reported. The reaction proceeds under mild conditions and uses tetralds(N,N-dimethylamino)ethylene as a terminal organic reductant. Good functional group tolerance is demonstrated, with over 20 examples of reactions that proceed with >90% ee.
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