Journal
ORGANIC LETTERS
Volume 19, Issue 2, Pages 304-307Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03276
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Funding
- Department of Science and Technology, New Delhi [EMR/2015/002332]
- IIT Ropar
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Lewis acid catalyzed [3 + 2]-cycloaddition reaction of donor-acceptor cyclopropanes with vinyl azides has been developed to obtain diastereomerically enriched azidocyclopentane derivatives. In addition, thermal chemoselective ring expansion of azidocyclopentanes to tetrahydropyridine derivatives and further diastereospecific reduction to a substituted piperidine derivative, with an excellent yield, was also achieved.
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