Journal
ORGANIC LETTERS
Volume 19, Issue 19, Pages 5178-5181Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02450
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Funding
- National Natural Science Foundation of China [21531004, 21472086]
- Major State Basic Research Development Program of China [2013CB922100]
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An efficient pyridyl-directed Rh(III)-Catalyzed o-carborane B(3)-H acyloxylation is reported. The:B(3)-H bond is the most electron-deficient vertex on o-carborane whose functionalization is challenging. The combination of Cu(OH)(2) and diverse carboxylic acids provides low cost and abundant acyloxyl sources which could lead to moderate to excellent yields.
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