Journal
ORGANIC LETTERS
Volume 20, Issue 1, Pages 36-39Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03256
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Funding
- Latsis Foundation programme EPISTHMONIKES MELETES (PhotoOrganocatalysis: Development of new environmentally friendly methods for the synthesis of compounds for the pharmaceutical and chemical industry)
- Hellenic Foundation for Research and Innovation (ELambdaIDeltaEK)
- National Scholarship Foundation
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A mild photocatalytic manifold for the synthesis of gamma-lactones has been developed. Utilizing Ru(bpy)(3)Cl-2 as the photocatalyst, a cheap and reproducible synthetic protocol for gamma-lactones has been introduced. Mechanistic studies revealed the successful monitoring of photocatalytic reactions and radical intermediates via high-resolution mass spectrometry.
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