Journal
ORGANIC LETTERS
Volume 19, Issue 20, Pages 5669-5672Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02837
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- University at Albany, State University of New York
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The development of visible-light-mediated synthesis of pyrroldindolines via an amidyl radical cyclization-carbon radical functionalization cascade is reported. The transformation shows a broad substrate scope, tolerating a variety of substitutions on indole aromatic rings and N-centers. Different functionalized alkene systems could be used as radical acceptors. Relying on this strategy, a rapid synthesis of flustramide B was achieved.
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