Journal
ORGANIC LETTERS
Volume 19, Issue 5, Pages 1188-1191Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00248
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Foundation for Innovation (CFI)
- provincial government of Quebec (FQRNT and CCVC)
- Programme Canadien de Bourses de la Francophonie
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A new stereoselective arylative cyclopropanation process involving treatment of halogenated dienone systems in the presence of a Michael donor containing a nitroaryl-sulfone has been developed. This transformation enables production of an arylated cyclopropane under mild conditions and occurs via a Michael Smiles ring closure cascade process, reflecting the concepts of green chemistry and atom economy.
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