Journal
ORGANIC LETTERS
Volume 19, Issue 22, Pages 6164-6167Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03073
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Funding
- Nanjing Tech University [39837110]
- SICAM Fellowship by Jiangsu National Synergetic Innovation Center for Advanced Materials
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A visible-light-engaged 2-fold site-selective alkylation of indole derivatives with aliphatic ethers or alcohols has been accomplished for easy access to symmetric 3,3'-bisindolylmethane derivatives. The experimental data suggest a sequential photoredox catalysis induced radical addition and proton-mediated Friedel-Crafts alkylation mechanism.
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