Journal
ORGANIC LETTERS
Volume 19, Issue 8, Pages 2094-2097Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00691
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Funding
- National Natural Science Foundation of China [21202092]
- Startup Foundation from the China Three Gorges University [KJ2012B080, KJ2014H008]
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A facile asymmetric transfer hydrogenation of ortho-substituted aryl N-heteroaryl ketones and non-ortho-substituted N-oxide of aryl N-heteroaryl ketones using a readily available oxo-tethered ruthenium complex as a catalyst and sodium formate as a hydrogen source in an aqueous solution has been discovered. A variety of chiral aryl N-heteroaryl methanols were obtained with up to 99.9% ee.
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