Journal
ORGANIC LETTERS
Volume 19, Issue 10, Pages 2596-2599Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00914
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Funding
- National Natural Science Foundation of China [NSFC21502232]
- Natural Science Foundation of Jiangsu Province [BK20140655]
- Foundation of State Key Laboratory of Natural Medicines [ZZYQ201605]
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A novel [3 + 3] cycloaddition between in situ formed azaoxyallyl cations and 2-alkenylindoles has been developed. This concise method allows the efficient construction of a series of tetrahydro-beta-carbolinones in good yields under mild conditions. Gram-scale experiments and further derivatization of tetrahydro-beta-carbolinones highlighted the potential utility of our method.
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