Journal
ORGANIC LETTERS
Volume 19, Issue 4, Pages 946-949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00168
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Funding
- National Natural Science Foundation of China [21576041, 21376040, 21231003]
- program for Changjiang Scholars and Innovative Research Team in University [IRT13008]
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The first ferrous chloride catalyzed boration/beta-fluorine elimination of trifluoromethyl alkenes is described. Thus, a full range of gem-difluoroallylboronates were obtained in high yield under mild conditions. As an important fluorinated building block, gem-difluoroallylboronate can be readily converted into diverse difluoro-substituted species.
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