Journal
ORGANIC LETTERS
Volume 19, Issue 4, Pages 798-801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03763
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Funding
- National Natural Science Foundation of China [NSFC-21572178, NSFC-21272185]
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The palladium-catalyzed intramolecular C-H/C-H coupling reaction of two simple arenes to generate 6H-benzo[c]chromenes has been reported for the first time. The approach features broad substrate scope and good tolerance of functional groups and uses molecular oxygen as the terminal oxidant. The high efficiency of the approach is verified by concise total synthesis of natural product cannabinol.
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