Journal
ORGANIC LETTERS
Volume 19, Issue 22, Pages 6184-6187Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03099
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Funding
- NSFC [21472186, 21525208]
- fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
- Strategic Priority Program of the CAS [XDB17020300]
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A Rh(III)-catalyzed site-selective C-H activation of C(3)-functionalized indoles in a coupling with diazo esters has been realized with carbonyl as a weakly coordinating group. The coupling selectivity is dictated by the temperature and additives, affording either C4-alkylated indoles or C2-annulated lactones in moderate to excellent efficiency.
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