Journal
ORGANIC LETTERS
Volume 19, Issue 20, Pages 5605-5608Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02721
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Funding
- TIFR Centre for Interdisciplinary Science Hyderabad, Hyderabad, India
- SERB-DST, India [EMR/2014/001237]
- Department of Science and Technology, New Delhi, India
- SERB-DST [EMR/2014/000247]
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Herein, the isolation and characterization of N-peralkyl-substituted NHCCAAC derived triazaalkenes in three oxidation states, neutral, radical cation, and dication, are reported. Cyclic voltammetry has shown the reversible electronic coupling between the first and second oxidation to be Delta E-1/2 = 0.50 V. As a proof-of-principle, to demonstrate the electron-rich nature of the triazaalkene, it was shown that it can be used as an electron donor in the reduction of an aryldiazonium salt to the corresponding arene.
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