Journal
ORGANIC LETTERS
Volume 19, Issue 19, Pages 5204-5207Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02477
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Funding
- Grants-in-Aid for Scientific Research [17K05817] Funding Source: KAKEN
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The N-heterocyclic-carbene-ligated ruthenium complex [RuHCl(CO)(H(2)IMes)(PCy3)] exhibits high catalytic activity for the (Z)-selective hydrosilylation of various terminal alkynes with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HSiMe-(OSiMe3)(2)). The stereoretentive derivatization of the (Z)-alkenylsiloxanes allows the synthesis of biologically active compounds, e.g. potent antitumor agents and inhibitors for induced-NO synthase.
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