Journal
ORGANIC LETTERS
Volume 19, Issue 4, Pages 966-968Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00174
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Funding
- Robert A. Welch Foundation [F-0038]
- NIH NIGMS [RO1-GM069445]
- UT Austin Center for Green Chemistry and Catalysis
- China Scholarship Council
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Upon exposure to a ruthenium(0) catalyst, N-benzy1-3-hydroxy-2-oxindoles react with diverse alkynes to form products of C-H vinylation with complete control of regioselectivity and olefin geometry. This method contributes to a growing body of catalytic processes that enable direct conversion of lower alcohols to higher alcohols in the absence of stoichiometric organometallic reagents.
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